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In the event that you need to scan your computer urgently you can do manually in the path: C:\Program Files\Total Network Inventory copies "tniwinagent.exe" file locally on your computer to scan, run it as administrator and will generate the file for the database TNI, you must place this file into your inventory.

I recommend that, being the case of Windows 7 on the part of: Control Panel --- System and Security --- Windows Firewall and Advanced Settings Rules of entry and exit options you enable (SMB) I hope that this can solve the problem. It is important that you do the scan with an administrator account and the TNI when registering must precede the credential: domain\user